| Australian Open |
| 2009-02-01 | Final | R. Nadal | 3-2 | R. Federer |  7-5 | 3-6 | 7-6 | 3-6 | 6-2 |
| Wimbledon |
| 2008-07-06 | Final | R. Federer | 2-3 | R. Nadal | 4-6 | 4-6 | 7-6 | 7-6 | 7-9 |
| Roland Garros |
| 2008-06-08 | Final | R. Federer | 0-3 | R. Nadal | 1-6 | 3-6 | 0-6 | | |
| Masters Series Hamburg |
| 2008-05-18 | Final | R. Federer | 1-2 | R. Nadal | 5-7 | 7-6 | 3-6 | | |
| Masters Series Monte Carlo |
| 2008-04-27 | Final | R. Federer | 0-2 | R. Nadal | 5-7 | 5-7 | | | |
| Barclays ATP World Tour Finals final stage |
| 2007-11-17 | Semifinals | R. Federer | 2-0 | R. Nadal | 6-4 | 6-1 | | | |
| Wimbledon |
| 2007-07-08 | Final | R. Federer | 3-2 | R. Nadal | 7-6 | 4-6 | 7-6 | 2-6 | 6-2 |
| Roland Garros |
| 2007-06-10 | Final | R. Federer | 1-3 | R. Nadal | 3-6 | 6-4 | 3-6 | 4-6 | |
| Masters Series Hamburg |
| 2007-05-20 | Final | R. Federer | 2-1 | R. Nadal | 2-6 | 6-2 | 6-0 | | |
| Masters Series Monte Carlo |
| 2007-04-22 | Final | R. Federer | 0-2 | R. Nadal | 4-6 | 4-6 | | | |
| Barclays ATP World Tour Finals final stage |
| 2006-11-18 | Semifinals | R. Federer | 2-0 | R. Nadal | 6-4 | 7-5 | | | |
| Wimbledon |
| 2006-07-09 | Final | R. Federer | 3-1 | R. Nadal | 6-0 | 7-6 | 6-7 | 6-3 | |
| Roland Garros |
| 2006-06-11 | Final | R. Federer | 1-3 | R. Nadal | 6-1 | 1-6 | 4-6 | 6-7 | |
| Campionati Internazionali d'Italia |
| 2006-05-14 | Final | R. Federer | 2-3 | R. Nadal | 7-6 | 6-7 | 4-6 | 6-2 | 6-7 |
| Masters Series Monte Carlo |
| 2006-04-23 | Final | R. Federer | 1-3 | R. Nadal | 2-6 | 7-6 | 3-6 | 6-7 | |
